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- W2326696075 abstract "Novel silicone elastomer was obtained by cross-linking reaction of thermal hydrosilylation reaction between poly(oxysilphenylenesiloxydisiloxane) having vinyl groups in side chain and SiH-terminated hyperbranched polycarbosiloxane. In situ measurements using solid-state 1H NMR were performed during the cross-linking reaction on heating. The results suggest that the cross-linking reaction was accelerated beyond 110 °C. Two overlapping reaction mechanisms reflect the characteristic molecular structures of poly(oxysilphenylenesiloxydisiloxane) having vinyl groups and SiH-terminated hyperbranched polycarbosiloxane. A possible structural model to satisfy both reaction mechanisms is proposed to characterize the development of the cross-linking reaction." @default.
- W2326696075 created "2016-06-24" @default.
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- W2326696075 date "2014-01-28" @default.
- W2326696075 modified "2023-09-23" @default.
- W2326696075 title "<i>In Situ</i> NMR Measurement of Novel Silicone Elastomer Obtained by Cross-Linking of Silicones Having Phenylene Backbone and Hyperbranched Molecular Architectures" @default.
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- W2326696075 doi "https://doi.org/10.1021/ma402291e" @default.
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