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- W2326729000 abstract "The ceria-supported rhenium catalyst modified with palladium (ReOx–Pd/CeO2 (Re = 2 wt %, Pd/Re = 0.25)) is still the best catalyst for simultaneous hydrodeoxygenation. Higher Re loading amount decreased the activity. The simultaneous hydrodeoxygenation of cyclic vicinal diols occurs with high cis-stereoselectivity. ReOx–Pd/CeO2 catalysts were characterized by means of XRD, TEM, H2-TPR, XAFS, XPS, Raman, and DFT calculations. The Re species on ReOx–Pd/CeO2 (Re = 2 wt %, Pd/Re = 0.25) catalyst after reduction and after stoichiometric reaction of 1,2-hexanediol to 1-hexene were ReIV and ReVI, and the ReIV species were converted to ReVI through the stoichiometric reaction. The Re species on ReOx–Pd/CeO2 are proposed to be randomly located on the CeO2 surface, and probably only monomeric Re species have catalytic activity for simultaneous hydrodeoxygenation. This model can explain the higher activity of Re = 2 wt % catalyst than those of higher Re loading catalysts. The reaction is proposed to proceed by the tetra/hexavalent redox cycle of the Re center in the catalysis followed by hydrogenation." @default.
- W2326729000 created "2016-06-24" @default.
- W2326729000 creator A5053881651 @default.
- W2326729000 creator A5053906254 @default.
- W2326729000 creator A5053930737 @default.
- W2326729000 creator A5070105971 @default.
- W2326729000 creator A5074282622 @default.
- W2326729000 date "2016-04-20" @default.
- W2326729000 modified "2023-09-27" @default.
- W2326729000 title "Performance, Structure, and Mechanism of ReO<sub><i>x</i></sub>–Pd/CeO<sub>2</sub> Catalyst for Simultaneous Removal of Vicinal OH Groups with H<sub>2</sub>" @default.
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- W2326729000 doi "https://doi.org/10.1021/acscatal.6b00491" @default.
- W2326729000 hasPublicationYear "2016" @default.
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