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- W2326778858 abstract "Zirconium/nickel comediated one-pot three-component cascade cyclization of carboryne, alkene, and 2-bromophenyltrimethylsilylacetylene has been achieved, leading to the formation of a series of C,C,B-substituted carborane-fused tricyclics. On the basis of experimental results, a plausible mechanism is proposed including [2 + 2 + 1] cross-cyclotrimerization followed by intramolecular direct selective cage B–C(sp2) coupling. This represents the first example of direct cage B–C(phenyl) coupling via cage B–H activation." @default.
- W2326778858 created "2016-06-24" @default.
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- W2326778858 date "2014-05-16" @default.
- W2326778858 modified "2023-09-25" @default.
- W2326778858 title "Transition-Metal-Mediated Three-Component Cascade Cyclization: Selective Cage B–C(sp<sup>2</sup>) Coupling of Carborane with Aromatics and Synthesis of Carborane-Fused Tricyclics" @default.
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- W2326778858 doi "https://doi.org/10.1021/ja503489b" @default.
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