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• W2326796654 abstract "We report the X-ray structure of a cyclohexanethiolate-capped [Au23(SR)16](-) nanocluster (counterion: tetraoctylammonium, TOA(+)). The structure comprises a cuboctahedron-based bipyramidal Au15 kernel, which is protected by two staple-like trimeric Au3(SR)4 motifs, two monomeric Au(SR)2 and four plain bridging SR ligands. Electronic structure analysis reveals nonsuperatomic feature of [Au23(SR)16](-) and confirms the Au15 kernel and surface motifs. The Au15 kernel and trimeric staple motif are unprecedented and offer new insight in understanding the structure evolution of gold nanoclusters." @default.
• W2326796654 created "2016-06-24" @default.
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• W2326796654 date "2013-11-25" @default.
• W2326796654 modified "2023-10-16" @default.
• W2326796654 title "Nonsuperatomic [Au₂₃(SC₆H₁₁)₁₆]⁻ Nanocluster Featuring Bipyramidal Au₁₅ Kernel and Trimeric Au₃(SR)₄ Motif" @default.
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• W2326796654 doi "https://doi.org/10.1021/ja409177s" @default.
• W2326796654 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24274138" @default.
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