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- W2326904059 abstract "Sr 0.5 Zr 2 (AsO 4 ) 3 arsenate was prepared and structurally characterized by powder X-ray diffraction and by Raman and infrared spectroscopies. Its structure, which belongs to the Nasicon-type family, was refined by the Rietveld method in the R-3 space group, from X-ray powder diffraction data. The hexagonal unit-cell parameters were determined to be a h =8.965(2) Å, c h =23.955(6) Å, V =1667.43(6) Å 3 , and Z =6. The structure is formed by an ionic three-dimensional network of AsO 4 tetrahedra and ZrO 6 octahedra linked by corners with Sr 2+ ions occupying half of the M1 sites in an ordered manner. Raman and infrared spectra were recorded and assignments of the stretching and bending vibrations of the AsO 4 3− tetrahedra were made. The number of the peaks observed is in good agreement with that predicted by the factor-group analysis of the R-3 space group." @default.
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- W2326904059 date "2009-09-01" @default.
- W2326904059 modified "2023-10-01" @default.
- W2326904059 title "Synthesis, crystal structure and vibrational spectra of Sr<sub>0.5</sub>Zr<sub>2</sub>(AsO<sub>4</sub>)<sub>3</sub>" @default.
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- W2326904059 doi "https://doi.org/10.1154/1.3187160" @default.
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