FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2326948311> ?p ?o ?g. }

• W2326948311 endingPage "769" @default.
• W2326948311 startingPage "762" @default.
• W2326948311 abstract "Reactions of (phenylethynyl)germylene LGeC≡CPh (L = HC[C(Me)N-2,6-iPr2C6H3]2) with 0.25 equiv of (CuC6F5)4, 1 equiv of AgC6F5·MeCN, and 1 equiv of AuC6F5·SC4H8, respectively, yielded LGe(C≡CPh)CuC6F5 (1), [(LGeC≡CPh)2Ag]+[Ag(C6F5)2]− (2), and LGe(C≡CPh)AuC6F5 (3). Complexes 1–3 were characterized by IR and NMR spectroscopy and X-ray crystallography. Compound 1 shows a bonding pattern of the CuC6F5 entity by both the phenylethynyl C≡C linkage and the L ligand backbone of the γ-C atom, while 3 exhibits a bonding mode of the AuC6F5 entity at the germylene center. Compound 2 is an ionic derivative featuring the Ge–Ag donor–acceptor bond formed under redistribution of the AgC6F5 entity. Further reactions of 1 with (CuC6F5)4, AgC6F5·MeCN, and AuC6F5·SC4H8 afforded the complexes LGe(C≡CPh)(CuC6F5)(MC6F5) (M = Cu (4), Ag (5), Au (6)). Compounds 4–6 were characterized by IR and NMR spectroscopy, and 5 and 6 were further investigated by X-ray crystallography. Compounds 4–6 all show an additional bonding of the respective MC6F5 moiety at the germylene center of 1. These studies reveal a multiple donor reactivity of LGeC≡CPh. The slightly different Lewis acidic properties of the congeneric pentafluorophenylcopper(I), -silver(I), and -gold(I) complexes as acceptors are thus disclosed." @default.
• W2326948311 created "2016-06-24" @default.
• W2326948311 creator A5035998690 @default.
• W2326948311 creator A5038327626 @default.
• W2326948311 creator A5057863584 @default.
• W2326948311 creator A5079199756 @default.
• W2326948311 creator A5081316842 @default.
• W2326948311 creator A5086057692 @default.
• W2326948311 creator A5086103973 @default.
• W2326948311 date "2013-01-24" @default.
• W2326948311 modified "2023-10-07" @default.
• W2326948311 title "Reactivity Studies of (Phenylethynyl)germylene LGeC≡CPh (L = HC[C(Me)N-2,6-<i>i</i>Pr₂C₆H₃]₂) toward Pentafluorophenylcopper(I), -silver(I), and -gold(I) Complexes" @default.
• W2326948311 cites W1908223592 @default.
• W2326948311 cites W1964788713 @default.
• W2326948311 cites W1966296282 @default.
• W2326948311 cites W1966690187 @default.
• W2326948311 cites W1968494659 @default.
• W2326948311 cites W1969111261 @default.
• W2326948311 cites W1971341850 @default.
• W2326948311 cites W1971436478 @default.
• W2326948311 cites W1971759988 @default.
• W2326948311 cites W1971771722 @default.
• W2326948311 cites W1972244400 @default.
• W2326948311 cites W1973030773 @default.
• W2326948311 cites W1973661839 @default.
• W2326948311 cites W1975904638 @default.
• W2326948311 cites W1978141406 @default.
• W2326948311 cites W1982100202 @default.
• W2326948311 cites W1985290183 @default.
• W2326948311 cites W1986411592 @default.
• W2326948311 cites W1987584935 @default.
• W2326948311 cites W1991757137 @default.
• W2326948311 cites W1995657280 @default.
• W2326948311 cites W1997143370 @default.
• W2326948311 cites W1999773198 @default.
• W2326948311 cites W2010999953 @default.
• W2326948311 cites W2016428799 @default.
• W2326948311 cites W2017347157 @default.
• W2326948311 cites W2018552790 @default.
• W2326948311 cites W2021864161 @default.
• W2326948311 cites W2023299920 @default.
• W2326948311 cites W2027493030 @default.
• W2326948311 cites W2028644788 @default.
• W2326948311 cites W2030249400 @default.
• W2326948311 cites W2030885443 @default.
• W2326948311 cites W2035010758 @default.
• W2326948311 cites W2039566409 @default.
• W2326948311 cites W2039651933 @default.
• W2326948311 cites W2039896776 @default.
• W2326948311 cites W2040807756 @default.
• W2326948311 cites W2041572995 @default.
• W2326948311 cites W2042515192 @default.
• W2326948311 cites W2045402927 @default.
• W2326948311 cites W2051451384 @default.
• W2326948311 cites W2055207935 @default.
• W2326948311 cites W2058170602 @default.
• W2326948311 cites W2059718353 @default.
• W2326948311 cites W2061124361 @default.
• W2326948311 cites W2065472254 @default.
• W2326948311 cites W2067360198 @default.
• W2326948311 cites W2069583611 @default.
• W2326948311 cites W2074353903 @default.
• W2326948311 cites W2078569185 @default.
• W2326948311 cites W2079046473 @default.
• W2326948311 cites W2079479448 @default.
• W2326948311 cites W2079765212 @default.
• W2326948311 cites W2100627556 @default.
• W2326948311 cites W2104246276 @default.
• W2326948311 cites W2106494246 @default.
• W2326948311 cites W2144640096 @default.
• W2326948311 cites W2148066840 @default.
• W2326948311 cites W2164720315 @default.
• W2326948311 cites W2279760770 @default.
• W2326948311 cites W2316814048 @default.
• W2326948311 cites W2329044488 @default.
• W2326948311 cites W2329838761 @default.
• W2326948311 cites W2950591610 @default.
• W2326948311 cites W4237402791 @default.
• W2326948311 cites W4256214021 @default.
• W2326948311 cites W4302372063 @default.
• W2326948311 doi "https://doi.org/10.1021/om300724t" @default.
• W2326948311 hasPublicationYear "2013" @default.
• W2326948311 type Work @default.
• W2326948311 sameAs 2326948311 @default.
• W2326948311 citedByCount "42" @default.
• W2326948311 countsByYear W23269483112013 @default.
• W2326948311 countsByYear W23269483112014 @default.
• W2326948311 countsByYear W23269483112015 @default.
• W2326948311 countsByYear W23269483112016 @default.
• W2326948311 countsByYear W23269483112017 @default.
• W2326948311 countsByYear W23269483112018 @default.
• W2326948311 countsByYear W23269483112019 @default.
• W2326948311 countsByYear W23269483112021 @default.
• W2326948311 countsByYear W23269483112022 @default.
• W2326948311 countsByYear W23269483112023 @default.
• W2326948311 crossrefType "journal-article" @default.
• W2326948311 hasAuthorship W2326948311A5035998690 @default.
• W2326948311 hasAuthorship W2326948311A5038327626 @default.

• next