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- W2326950553 endingPage "4951" @default.
- W2326950553 startingPage "4948" @default.
- W2326950553 abstract "A novel synthesis of substituted pyrroles by a gold(I)-catalyzed cascade reaction has been developed. The reaction proceeded with an autotandem catalysis consisting of an initial addition of gold–acetylide to an acetal moiety and was followed by gold-catalyzed 5-endo-dig cyclization and aromatization. Gold catalysts play a dual role in activating nucleophilicity or electrophilicity of terminal acetylenes by forming gold–acetylides or by π-coordination. The formal (3 + 2) annulation of two components provided a variety of substituted pyrroles in a modular fashion." @default.
- W2326950553 created "2016-06-24" @default.
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- W2326950553 date "2014-09-09" @default.
- W2326950553 modified "2023-10-16" @default.
- W2326950553 title "Autotandem Catalysis: Synthesis of Pyrroles by Gold-Catalyzed Cascade Reaction" @default.
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- W2326950553 doi "https://doi.org/10.1021/ol5024695" @default.
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