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- W2327005163 abstract "The oxidative addition of secondary electrophiles to Pd(0) is significantly accelerated by anomeric effects. In contrast to cyclohexyl bromide, acetobromo-α-d-glucose undergoes invertive oxidative addition to tris(triethylphosphine)palladium(0) to generate a stable, isolable organometallic complex, Pd(PEt3)2(Br)(AcO-β-glucose), which has been fully characterized but is prone to β-acetoxy elimination." @default.
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- W2327005163 date "2011-04-19" @default.
- W2327005163 modified "2023-09-23" @default.
- W2327005163 title "Oxidative Addition of Secondary C–X Bonds to Palladium(0): A Beneficial Anomeric Acceleration" @default.
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- W2327005163 doi "https://doi.org/10.1021/om200221r" @default.
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