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• W2327040567 abstract "Silica gel (60–120 mesh) efficiently catalyses the opening of epoxide rings by amines at rt under solvent-free conditions providing an easy method for the synthesis of 2-amino alcohols. Aromatic and aliphatic amines react with cyclohexene oxide with exclusive formation of the trans-2-aryl/alkylaminocyclohexanols in high yields. A complementary regioselectivity is exhibited by aromatic and aliphatic amines during the reaction with styrene oxide. The epoxide ring of non-styrenoidal unsymmetrical alkene oxide undergoes selective nucleophilic attack at the sterically less hindered carbon by aniline." @default.
• W2327040567 created "2016-06-24" @default.
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• W2327040567 date "2004-01-01" @default.
• W2327040567 modified "2023-09-30" @default.
• W2327040567 title "An efficient synthesis of 2-amino alcohols by silica gel catalysed opening of epoxide rings by amines" @default.
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• W2327040567 doi "https://doi.org/10.1039/b400588k" @default.
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