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- W2327059072 abstract "The crystal structures of two new compounds (H 3 O) 2 ((UO 2 )(SeO 4 ) 2 (H 2 O))(H 2 O) 2 ( 1 , orthorhom- bic, Pnma , a = 14.0328(18), b = 11.6412(13), c = 8.2146(13) A, V = 134.9(3) A 3 ) and (H 3 O) 2 ((UO 2 )(SeO 4 ) 2 (H 2 O))(H 2 O) ( 2 , monoclinic, P 2 1 / c , a = 7.8670(12), b = 7.5357(7), c = 21.386(3) A, β = 101.484(12) ° , V = 1242.5(3) A 3 ) have been solved by direct methods and refined to R 1 = 0.076 and 0.080, respectively. The structures of both compounds contain sheet complexes ((UO 2 )(SeO 4 ) 2 ) 2- formed by corner- shared ((UO 2 )O 4 (H 2 O)) bipyramids and SeO 4 tetrahedrons. The sheets are parallel to the (100) plane in struc- ture 1 and to (-102) in structure 2 . The ((UO 2 )(SeO 4 ) 2 (H 2 O)) 2- layers are linked by hydrogen bonds via inter- layer groups H 2 O and H 3 O + . The sheet topologies in structures 1 and 2 are different and correspond to the topol- ogies of octahedral and tetrahedral complexes in rhomboclase (H2O2) + (Fe(SO4)2(H2O)2) and goldichite K(Fe(SO4)2(H2O)2)(H2O)2, respectively." @default.
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- W2327059072 date "2008-01-01" @default.
- W2327059072 modified "2023-09-26" @default.
- W2327059072 title "Crystal Chemistry of Selenates with Mineral-Like Structures: V. Crystal Structures of (H 3 O) 2 ((UO 2 )(SeO 4 ) 2 (H 2 O))(H 2 O) 2 and (H 3 O) 2 ((UO 2 )(SeO 4 ) 2 (H 2 O))(H 2 O), New Compounds" @default.
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