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- W2327135220 abstract "Of the polymer materials investigated as anion exchange membranes, trimethylbenzylammonium-containing polysulfones are the most extensively studied. They are commonly prepared by chloromethylation of the aromatic backbone or radical bromination of benzylic carbons, followed by a Menshutkin reaction between a tertiary amine and the benzyl halide. To overcome synthetic limitations involved with these two methods, we report the preparation of an anion exchange membrane by means of iridium-catalyzed C–H borylation followed by palladium-catalyzed Suzuki coupling. Owing to the use of mild reaction conditions and high efficiency of these metal-catalyzed reactions, we were able to minimize side reactions and easily control the degree of functionalization for a series of trimethylbenzylammonium-containing polysulfones. The resulting membranes exhibited lower water uptake while maintaining similar hydroxide conductivity and functional group stability as compared to the corresponding chloromethylation-prepared anion exchange membrane materials." @default.
- W2327135220 created "2016-06-24" @default.
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- W2327135220 date "2014-03-11" @default.
- W2327135220 modified "2023-09-23" @default.
- W2327135220 title "Anion Exchange Fuel Cell Membranes Prepared from C–H Borylation and Suzuki Coupling Reactions" @default.
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- W2327135220 doi "https://doi.org/10.1021/ma500125t" @default.
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