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• W2327138840 abstract "Unnatural (R)-α-amino acids (α-AAs) are in growing demand in the biomedical research and pharmaceutical industries. In this work, we present development of a purely chemical approach for preparation of (R)-α-AAs via (S)-to-(R)-interconversion of natural and tailor-made (S)-α-AAs. The method can be used on free, unprotected α-AAs and features a remarkable structural generality including substrates bearing tertiary alkyl chains and reactive functional groups. These attractive characteristics, combined with simplicity of reaction conditions and virtually complete stereochemical outcome, constitute a true methodological advance in this area, rivaling previously reported chemical and biocatalytic approaches." @default.
• W2327138840 created "2016-06-24" @default.
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• W2327138840 date "2016-04-18" @default.
• W2327138840 modified "2023-10-14" @default.
• W2327138840 title "Purely Chemical Approach for Preparation of<scp>d</scp>-α-Amino Acids via (<i>S</i>)-to-(<i>R</i>)-Interconversion of Unprotected Tailor-Made α-Amino Acids" @default.
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• W2327138840 doi "https://doi.org/10.1021/acs.joc.5b02707" @default.
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