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• W2327177910 endingPage "6195" @default.
• W2327177910 startingPage "6186" @default.
• W2327177910 abstract "Planar neutral organometallic complexes have the potential to be exploited as building blocks for the construction of self-assembled nanoscale materials. We report the synthesis and first structural characterization of planar pyridyl gold(I) alkynyl complexes. Stable isolable complexes are only obtained when electron-rich pyridine ligands such as 4-(dimethylamino)pyridine or 4-aminopyridine are incorporated into the complexes. X-ray crystallography confirms that the pyridyl gold(I) alkynyls are neutral, linear, two-coordinate complexes. Furthermore, these gold(I) molecules form dimers in the solid state. However, no aurophilic interactions are observed to stabilize the solid-state structures. Density functional theory (DFT) calculations have been employed to model the electronic structure and thermodynamics of formation for selected complexes." @default.
• W2327177910 created "2016-06-24" @default.
• W2327177910 creator A5018372186 @default.
• W2327177910 creator A5028089575 @default.
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• W2327177910 creator A5038826827 @default.
• W2327177910 creator A5069108292 @default.
• W2327177910 creator A5075147918 @default.
• W2327177910 date "2010-10-29" @default.
• W2327177910 modified "2023-10-07" @default.
• W2327177910 title "Pyridyl Gold(I) Alkynyls: A Synthetic, Structural, Spectroscopic, and Computational Study" @default.
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