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- W23273485 abstract "Abstract Adsorption isotherms, together with microcalorimetrie data comprising differential enthalpies of adsorption of carbon dioxide at 311 K and of nitrogen and argon at 77 K, as well as enthalpies of immersion in benzene and other organic liquids differing in shape and molecular size, were used to evaluate the microporosity of a series of carbon, characterized by systematic changes of their capillary structure (steam activated brown coal humic acids chars). In chars of low burn-offs the entire microporosity is contained in primary micropores. With increasing burn-offs secondary microporosity appears and the molecular sieve properties of the chars diminish. The mechanism of carbon dioxide adsorption at room temperature seems to differ from that of other adsorbates: for burn-offs between 10 and 75% the micropore volumes calculated from carbon dioxide adsorption are almost constant (0.21 – 0.25 cm 3 .g −1 ), while respective values from adsorption of benzene are 0.13 – 0.50 cm 3 .g −l , and from nitrogen, also argon, 0.14 – 0.53 cm 3 .g −l." @default.
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- W23273485 date "1988-01-01" @default.
- W23273485 modified "2023-09-25" @default.
- W23273485 title "Adsorption of Carbon Dioxide, Benzene, Nitrogen and Argon by Microporous Carbons: Interpretation of Isotherms and Enthalpies of Adsorption and Immersion" @default.
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- W23273485 doi "https://doi.org/10.1016/s0167-2991(09)60771-0" @default.
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