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- W2327432034 abstract "The properties of different Au(III) halo dithiocarbamate complexes of structure [AuX2(S2CN(R)2)] as suitable catalysts for the hydration reaction of phenylacetylene have been tested. Moderate catalytic activity was found for X = Cl, Br, while those compounds in which X = I, C6F5 are inert. A working mechanism involving the initial dissociation of a labile ligand (Cl or Br) followed by coordination and activation of the alkyne, solvent-assisted attack of water, and enol tautomerization has been proposed through computational studies." @default.
- W2327432034 created "2016-06-24" @default.
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- W2327432034 date "2014-07-16" @default.
- W2327432034 modified "2023-10-18" @default.
- W2327432034 title "Experimental and Theoretical Study of Gold(III)-Catalyzed Hydration of Alkynes" @default.
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- W2327432034 doi "https://doi.org/10.1021/om500523r" @default.
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