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- W2327437810 abstract "The synthesis and characterization of the amidinate-stabilized bisgermylene oxide and sulfide [L2Ge−E−GeL2] (E = O (2), S (3); L2 = ButC(NAr)2, Ar = 2,6-Pri2C6H3) are described. Compound 2 was prepared by the reaction of two equivalents of [L2GeCl] (1) with Me3NO and two equivalents of KC8 in THF. It is proposed that the reaction proceeds through an [L2GeI] intermediate, which then reacts with Me3NO to form 2. Similarly, the reaction of two equivalents of 1 with elemental sulfur and two equivalents of KC8 in THF afforded 3. Compounds 2 and 3 have been characterized by NMR spectroscopy and X-ray crystallography." @default.
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- W2327437810 date "2011-03-09" @default.
- W2327437810 modified "2023-10-18" @default.
- W2327437810 title "Synthesis and Characterization of an Amidinate-Stabilized Bisgermylene Oxide and Sulfide" @default.
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- W2327437810 doi "https://doi.org/10.1021/om101194f" @default.
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