Matches in SemOpenAlex for { <https://semopenalex.org/work/W2327465621> ?p ?o ?g. }
Showing items 1 to 78 of
78
with 100 items per page.
- W2327465621 endingPage "111" @default.
- W2327465621 startingPage "111" @default.
- W2327465621 abstract "Reactions of both axial and equatorial cholestan-3α- and -3β-yl mesylates and tosylates with sodium diarylphosphides give cholestanylphosphines in good yield and with complete inversion of stereochemistry. The stereochemistry has been established by an X-ray crystal structure of (5α-cholestan-3α-yl) diphenylphosphine oxide, and a general method for distinguishing between axial and equatorial phosphines based on 31P N.M.R . spectra is presented. The monophosphines were used as ligands in asymmetric hydrogenation, but only low optical yields were obtained." @default.
- W2327465621 created "2016-06-24" @default.
- W2327465621 creator A5018624230 @default.
- W2327465621 creator A5020300891 @default.
- W2327465621 creator A5070854089 @default.
- W2327465621 date "1985-01-01" @default.
- W2327465621 modified "2023-09-25" @default.
- W2327465621 title "The Stereochemistry of Organmetallic Compounds. XXV. The Stereochemistry of Displacements of Secondary Methanesulfonate and p-Toluene-sulfonate esters by Diphenylphosphide Ions. X-ray Crystal Structure of (5α- Cholestan- 3α-yl)diphenylphosphine Oxide" @default.
- W2327465621 doi "https://doi.org/10.1071/ch9850111" @default.
- W2327465621 hasPublicationYear "1985" @default.
- W2327465621 type Work @default.
- W2327465621 sameAs 2327465621 @default.
- W2327465621 citedByCount "4" @default.
- W2327465621 crossrefType "journal-article" @default.
- W2327465621 hasAuthorship W2327465621A5018624230 @default.
- W2327465621 hasAuthorship W2327465621A5020300891 @default.
- W2327465621 hasAuthorship W2327465621A5070854089 @default.
- W2327465621 hasConcept C115624301 @default.
- W2327465621 hasConcept C134121241 @default.
- W2327465621 hasConcept C145148216 @default.
- W2327465621 hasConcept C155647269 @default.
- W2327465621 hasConcept C161790260 @default.
- W2327465621 hasConcept C178790620 @default.
- W2327465621 hasConcept C185592680 @default.
- W2327465621 hasConcept C191503008 @default.
- W2327465621 hasConcept C191897082 @default.
- W2327465621 hasConcept C192562407 @default.
- W2327465621 hasConcept C2776416708 @default.
- W2327465621 hasConcept C2777716191 @default.
- W2327465621 hasConcept C2778142098 @default.
- W2327465621 hasConcept C2778894819 @default.
- W2327465621 hasConcept C2779851234 @default.
- W2327465621 hasConcept C2911096669 @default.
- W2327465621 hasConcept C537181965 @default.
- W2327465621 hasConcept C65024703 @default.
- W2327465621 hasConcept C71240020 @default.
- W2327465621 hasConcept C8010536 @default.
- W2327465621 hasConceptScore W2327465621C115624301 @default.
- W2327465621 hasConceptScore W2327465621C134121241 @default.
- W2327465621 hasConceptScore W2327465621C145148216 @default.
- W2327465621 hasConceptScore W2327465621C155647269 @default.
- W2327465621 hasConceptScore W2327465621C161790260 @default.
- W2327465621 hasConceptScore W2327465621C178790620 @default.
- W2327465621 hasConceptScore W2327465621C185592680 @default.
- W2327465621 hasConceptScore W2327465621C191503008 @default.
- W2327465621 hasConceptScore W2327465621C191897082 @default.
- W2327465621 hasConceptScore W2327465621C192562407 @default.
- W2327465621 hasConceptScore W2327465621C2776416708 @default.
- W2327465621 hasConceptScore W2327465621C2777716191 @default.
- W2327465621 hasConceptScore W2327465621C2778142098 @default.
- W2327465621 hasConceptScore W2327465621C2778894819 @default.
- W2327465621 hasConceptScore W2327465621C2779851234 @default.
- W2327465621 hasConceptScore W2327465621C2911096669 @default.
- W2327465621 hasConceptScore W2327465621C537181965 @default.
- W2327465621 hasConceptScore W2327465621C65024703 @default.
- W2327465621 hasConceptScore W2327465621C71240020 @default.
- W2327465621 hasConceptScore W2327465621C8010536 @default.
- W2327465621 hasIssue "1" @default.
- W2327465621 hasLocation W23274656211 @default.
- W2327465621 hasOpenAccess W2327465621 @default.
- W2327465621 hasPrimaryLocation W23274656211 @default.
- W2327465621 hasRelatedWork W1967938117 @default.
- W2327465621 hasRelatedWork W1990810784 @default.
- W2327465621 hasRelatedWork W2063794306 @default.
- W2327465621 hasRelatedWork W2093514242 @default.
- W2327465621 hasRelatedWork W2097014657 @default.
- W2327465621 hasRelatedWork W2327465621 @default.
- W2327465621 hasRelatedWork W2368810031 @default.
- W2327465621 hasRelatedWork W2951325620 @default.
- W2327465621 hasRelatedWork W2951834467 @default.
- W2327465621 hasRelatedWork W2951892583 @default.
- W2327465621 hasVolume "38" @default.
- W2327465621 isParatext "false" @default.
- W2327465621 isRetracted "false" @default.
- W2327465621 magId "2327465621" @default.
- W2327465621 workType "article" @default.