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• W2327499061 startingPage "10007" @default.
• W2327499061 abstract "Upon S0–S1 excitation, the pyrazoline derivative molecule (Z)-2-(4-nitrophenyl)-3-(1-phenyl-4,5-dihydro-1H-pyrazol-3-yl)acrylonitrile, abbreviated as PY-oCNNO2, can be transformed from its ground state trans (E) form to bended cis (Z) form. Similar to the case of the well-known family of the photochromic azobenzenes, such a molecular property can be employed to fabrication of photochromic polymers by suitable doping of the chromophores into polymer matrix. In this work, we prepared poly(methyl methacrylate) thin films doped with PY-oCNNO2 and measured the characteristic for optical switchers dynamic and static photoinduced birefringence (PIB) phenomenon. Possible conformational states of PY-oCNNO2, energy barriers, and associated dipole moments were calculated using TD-DFT quantum chemical methods. The presented experiments show that pyrazoline derivatives constitute a prospective group of materials with a great potential for photonic applications." @default.
• W2327499061 created "2016-06-24" @default.
• W2327499061 creator A5052341676 @default.
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• W2327499061 date "2015-04-28" @default.
• W2327499061 modified "2023-09-24" @default.
• W2327499061 title "Photoinduced Birefringence in PMMA Polymer Doped with Photoisomerizable Pyrazoline Derivative" @default.
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• W2327499061 doi "https://doi.org/10.1021/acs.jpcc.5b01947" @default.
• W2327499061 hasPublicationYear "2015" @default.
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