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- W2327658085 abstract "Enthalpies and entropies of activation have been derived from rate constants measured over a range of temperature for the dilute acid hydrolysis of isobutyramide, diethylacetamide, α-methylbutyramide, cyclohexaneoarboxamide, cyclopentane-carboxamide, and trimethylacetamide. ��� These data, in combination with data for other amides produced earlier, show the hydrolysis rate constants to be dominated by steric influences but with a perturbing effect which is proportional to the number of α-hydrogens present in the substituent. The α-hydrogen bonding concept of hyperconjugation appears to offer a reasonable explanation of these perturbations. ��� Controlled steric changes are shown to be non-additive for this reaction and to exert their influence primarily through the enthalpy component of the observed free energy changes." @default.
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- W2327658085 date "1971-01-01" @default.
- W2327658085 modified "2023-09-27" @default.
- W2327658085 title "Hydrolysis of amides. IV. Dilute acid hydrolysis of amides of the type R2CH-CONH2 and R3C-CONH2" @default.
- W2327658085 doi "https://doi.org/10.1071/ch9710471" @default.
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