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• W2327679667 abstract "We develop here a urea hydrolysis method to in situ prepare asymmetric ZnAl-CO3 layered double hydroxide (LDH) buffer layers with various stable equilibrium morphology on porous Al2O3 substrates. In particular it is found that well-intergrown ZIF-8 membranes can be directly synthesized on the ZnAl-CO3 LDH buffer layer-modified substrates, owing to the specific metal–imidazole interaction between ZnAl-CO3 LDHs and ZIF-8. Other Zn-based MOF membranes, like ZIF-7 and ZIF-90, can also be synthesized with this method. Our finding demonstrates that LDH buffer layer represents a new concept for substrate modification." @default.
• W2327679667 created "2016-06-24" @default.
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• W2327679667 date "2014-10-03" @default.
• W2327679667 modified "2023-10-18" @default.
• W2327679667 title "<i>In Situ</i> Synthesis of MOF Membranes on ZnAl-CO₃ LDH Buffer Layer-Modified Substrates" @default.
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• W2327679667 doi "https://doi.org/10.1021/ja507408s" @default.
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