Matches in SemOpenAlex for { <https://semopenalex.org/work/W2327688145> ?p ?o ?g. }
- W2327688145 endingPage "5167" @default.
- W2327688145 startingPage "5161" @default.
- W2327688145 abstract "Strong toluenesulfonic and triflic acids were incorporated into a MIL-101 chromium(III) terephthalate coordination framework, producing hybrid proton-conducting solid electrolytes. These acid@MIL hybrid materials possess stable crystalline structures that do not deteriorate during multiple measurements or prolonged heating. Particularly, the triflic-containing compound demonstrates the highest 0.08 S cm(-1) proton conductivity at 15% relative humidity and a temperature of 60 °C, exceeding any of today's commercial materials for proton-exchange membranes. The structure of the proton-conducting media, as well as the long-range proton-transfer mechanics, was unveiled, in a certain respect, by Fourier transform infrared and (1)H NMR spectroscopy investigations. The acidic media presumably constitutes large separated droplets, coexisting in the MIL nanocages. One component of proton transfer appears to be related to the facile relay (Grotthuss) mechanism through extensive hydrogen-bonding interactions within such droplets. The second component occurs during continuous reorganization of the droplets, thus ensuring long-range proton transfer along the porous structure of the material." @default.
- W2327688145 created "2016-06-24" @default.
- W2327688145 creator A5002710889 @default.
- W2327688145 creator A5020448997 @default.
- W2327688145 creator A5021615386 @default.
- W2327688145 creator A5022407961 @default.
- W2327688145 creator A5026696438 @default.
- W2327688145 creator A5029443182 @default.
- W2327688145 creator A5030206963 @default.
- W2327688145 creator A5033605018 @default.
- W2327688145 creator A5057395898 @default.
- W2327688145 creator A5075747576 @default.
- W2327688145 date "2014-03-31" @default.
- W2327688145 modified "2023-09-26" @default.
- W2327688145 title "High Proton Conductivity and Spectroscopic Investigations of Metal–Organic Framework Materials Impregnated by Strong Acids" @default.
- W2327688145 cites W1968029957 @default.
- W2327688145 cites W1968550114 @default.
- W2327688145 cites W1969232586 @default.
- W2327688145 cites W1970782643 @default.
- W2327688145 cites W1975178091 @default.
- W2327688145 cites W1976591333 @default.
- W2327688145 cites W1981825642 @default.
- W2327688145 cites W1985241939 @default.
- W2327688145 cites W1998045898 @default.
- W2327688145 cites W2004396881 @default.
- W2327688145 cites W2007661885 @default.
- W2327688145 cites W2013416944 @default.
- W2327688145 cites W2025346738 @default.
- W2327688145 cites W2026456752 @default.
- W2327688145 cites W2034709825 @default.
- W2327688145 cites W2035519584 @default.
- W2327688145 cites W2056556916 @default.
- W2327688145 cites W2059149370 @default.
- W2327688145 cites W2063153106 @default.
- W2327688145 cites W2066394349 @default.
- W2327688145 cites W2069220317 @default.
- W2327688145 cites W2070321532 @default.
- W2327688145 cites W2074011240 @default.
- W2327688145 cites W2078613814 @default.
- W2327688145 cites W2081636725 @default.
- W2327688145 cites W2085622132 @default.
- W2327688145 cites W2093266618 @default.
- W2327688145 cites W2094913492 @default.
- W2327688145 cites W2095159575 @default.
- W2327688145 cites W2114722820 @default.
- W2327688145 cites W2114798196 @default.
- W2327688145 cites W2127788559 @default.
- W2327688145 cites W2129375929 @default.
- W2327688145 cites W2133420487 @default.
- W2327688145 cites W2136222338 @default.
- W2327688145 cites W2146611563 @default.
- W2327688145 cites W2151546244 @default.
- W2327688145 cites W2157415871 @default.
- W2327688145 cites W2159898685 @default.
- W2327688145 cites W2168866411 @default.
- W2327688145 cites W2169398350 @default.
- W2327688145 cites W2316441214 @default.
- W2327688145 cites W2316458226 @default.
- W2327688145 cites W2320674404 @default.
- W2327688145 cites W2323084707 @default.
- W2327688145 cites W2335915808 @default.
- W2327688145 cites W4249652017 @default.
- W2327688145 cites W4366807521 @default.
- W2327688145 doi "https://doi.org/10.1021/am500438a" @default.
- W2327688145 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24641006" @default.
- W2327688145 hasPublicationYear "2014" @default.
- W2327688145 type Work @default.
- W2327688145 sameAs 2327688145 @default.
- W2327688145 citedByCount "86" @default.
- W2327688145 countsByYear W23276881452014 @default.
- W2327688145 countsByYear W23276881452015 @default.
- W2327688145 countsByYear W23276881452016 @default.
- W2327688145 countsByYear W23276881452017 @default.
- W2327688145 countsByYear W23276881452018 @default.
- W2327688145 countsByYear W23276881452019 @default.
- W2327688145 countsByYear W23276881452020 @default.
- W2327688145 countsByYear W23276881452021 @default.
- W2327688145 countsByYear W23276881452022 @default.
- W2327688145 countsByYear W23276881452023 @default.
- W2327688145 crossrefType "journal-article" @default.
- W2327688145 hasAuthorship W2327688145A5002710889 @default.
- W2327688145 hasAuthorship W2327688145A5020448997 @default.
- W2327688145 hasAuthorship W2327688145A5021615386 @default.
- W2327688145 hasAuthorship W2327688145A5022407961 @default.
- W2327688145 hasAuthorship W2327688145A5026696438 @default.
- W2327688145 hasAuthorship W2327688145A5029443182 @default.
- W2327688145 hasAuthorship W2327688145A5030206963 @default.
- W2327688145 hasAuthorship W2327688145A5033605018 @default.
- W2327688145 hasAuthorship W2327688145A5057395898 @default.
- W2327688145 hasAuthorship W2327688145A5075747576 @default.
- W2327688145 hasConcept C121332964 @default.
- W2327688145 hasConcept C127413603 @default.
- W2327688145 hasConcept C131540310 @default.
- W2327688145 hasConcept C147789679 @default.
- W2327688145 hasConcept C159467904 @default.
- W2327688145 hasConcept C161790260 @default.
- W2327688145 hasConcept C178790620 @default.
- W2327688145 hasConcept C185592680 @default.