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- W2327791388 abstract "Conical-shaped penta(aryl)[60]fullerene thiol derivatives bearing one alkyl thiol linker surrounded by five phenyl or biphenyl groups were synthesized in good yield, and characterized by X-ray crystallographic analysis. These conical fullerene thiols were used for formation of self-assembled monolayers (SAMs) on gold surface in anaerobic and aerobic condition. Under nitrogen atmosphere, SAMs on gold were successfully prepared for all thiols (C60Ph5(CH2)3SH, C60Ph5(CH2)4SH, C60Ph5(CH2)6SH, C60(biphenyl)5(CH2)6SH) used in this work. The SAMs of penta(aryl)[60]fullerene thiols exhibited anodic and cathodic photocurrent generation upon light irradiation (λ = 400 nm) in the presence of sacrificial electron-donating and -accepting reagents, respectively. The SAM formation under air gave either SAMs or aggregates on gold depending on the length of alkyl chains of the linker. When the linker is long enough (i.e., C60Ph5(CH2)6SH) so that the disulfide group is not sterically protected (i.e., C60Ph5(CH2)6S−S(CH2)6C60Ph5), the molecules formed SAMs and generated anodic and cathodic photocurrent. Further aggregation of the molecules occurred when the linker is short relative to the arene cone consisting of five aryl groups (i.e., C60Ph5(CH2)3SH). These aggregates showed unusual anodic photocurrent behavior, likely because of diffusion issue for electrolyte and sacrificial reagents. The aggregates were further investigated by cyclic voltammetry, atomic force microscopy, and photoelectron yield spectroscopy." @default.
- W2327791388 created "2016-06-24" @default.
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- W2327791388 date "2010-09-17" @default.
- W2327791388 modified "2023-10-13" @default.
- W2327791388 title "Conical Pentaaryl[60]fullerene Thiols: Self-Assembled Monolayers on Gold and Photocurrent Generating Property" @default.
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- W2327791388 doi "https://doi.org/10.1021/jp1059402" @default.
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