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• W2327816067 abstract "Synthesis of a series of (NHC)Pd(sal)Cl complexes, 1−5, bearing a salicylaldimine (sal) unit was described. The structure−reactivity relationship, especially the steric and electronic effects of the salicylaldimine ligands on their catalytic activities, was investigated intensively in the Buchwald−Hartwig coupling reaction. Our study demonstrated that the sterically encumbered N-aryl groups in the salicylaldimine unit give rise to an obviously negative effect in the aryl amination reaction. Additionally, incorporating a steric substituent into the ortho-position of the phenoxide oxygen atom does not appear to be beneficial to their catalytic activity. Notably, the electronic nature of N-substituted aryl groups in the salicylaldimine ligands plays a significant role in their catalytic activities. An electron-rich N-aryl group causes an obviously decreasing yield, while an electron-deficient one, such as complex 5b, leads to enhanced reactivity. The aryl amination reaction with complex 5b was also found to ..." @default.
• W2327816067 created "2016-06-24" @default.
• W2327816067 creator A5005774788 @default.
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• W2327816067 date "2010-11-02" @default.
• W2327816067 modified "2023-09-25" @default.
• W2327816067 title "Insight into the Steric and Electronic Effects of Ancillary Ligands: Synthesis and Structure−Reactivity Relationship of Well-Defined, Air- and Moisture-Stable (NHC)Pd(sal)Cl Complexes (sal = Salicylaldimine)" @default.
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• W2327816067 doi "https://doi.org/10.1021/om100906n" @default.
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