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- W2327831754 abstract "硫酸2- (ペルフルオロアルキル) エチル塩同族体CnF2n+1C2H4SO4M (M = Li, n = 4, 6, 8, 10 ; M = Na, n = 4, 6, 8) と, 比較のために, 硫酸アルキル塩同族体CmH2m+1SO4M (M = Li, Na, m = 8, 10, 12, 14) の水中における臨界ミセル濃度 (cmc) を測定し, 25℃のcmc値を, log cmc = A+Bn (or m) の形に表した。 CnF2n+1C2H4SO4MのB値は-0.44となり, これはcmc値はペルフルオロアルキル鎖のCF2基一つ当たり, 約2.8の因子で減少することを意味する。CnF2n+1C2H4SO4MとCmF2m+1SO4MのB値の比はほぼ1.5となる。 CnF2n+1C2H4SO4Mのcmcはおおよそm = 1.5n+2のCmF2m+1SO4Mのcmcに相当するとしてよい。C8F17C2H4SO4Naと C10F21C2H4SO4Naのクラフト点はそれぞれ46℃と67℃であった。" @default.
- W2327831754 created "2016-06-24" @default.
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- W2327831754 date "1996-01-01" @default.
- W2327831754 modified "2023-09-23" @default.
- W2327831754 title "Critical Micelle Concentrations for Homologs of 2-(Perfluoroalkyl)ethyl Sulfate Salts in Aqueous Solution." @default.
- W2327831754 doi "https://doi.org/10.5650/jos1996.45.1277" @default.
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