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- W2327833037 abstract "A bulky organoborane ArF2BMe (ArF = 2,4,6-tris(trifluoromethyl)phenyl, 1) has been synthesized. In C6D6 solution this organoborane and pyridine form a frustrated Lewis pair. Under mild conditions, 1 can efficiently catalyze 1,4-hydroboration of a series of pyridines. This reaction is highly chemo- and regioselective. The reaction intermediate, a boronium complex [Py2Bpin][ArF2B(H)Me] (3), was characterized in solution by NMR spectroscopy, which was also confirmed by DFT calculation." @default.
- W2327833037 created "2016-06-24" @default.
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- W2327833037 date "2015-04-10" @default.
- W2327833037 modified "2023-10-12" @default.
- W2327833037 title "Organoborane Catalyzed Regioselective 1,4-Hydroboration of Pyridines" @default.
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- W2327833037 doi "https://doi.org/10.1021/jacs.5b03147" @default.
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