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- W2327862318 abstract "A composite of bithiazole–benzothiadiazole-based semiconducting conjugated copolymer and gold nanoparticles (AuNPs) was prepared in situ and characterized by transmission electron microscopy, thermogravimetry, and UV–vis absorption spectroscopy. The polymer interacts with the nanoparticle surface through the nonbonding electrons of the nitrogen and sulfur atoms, which provides stability to the nanoparticles as well as planarity and rigidity to the polymer backbone. As a result, the effective conjugation length and delocalization of π-electrons of the polymer improved as evident from 130 nm red-shift in the UV–vis absorption spectrum. The nanoparticle along with the chemisorbed layer of polymer acts as a template for the self-assembly of the remaining polymer which is dispersed in the solution through π–π-stacking and van der Waals interactions. The self-assembly process enhances the polymer packing as well as ordering as seen from the shorter d spacing and from the more than threefold increase in the inte..." @default.
- W2327862318 created "2016-06-24" @default.
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- W2327862318 date "2012-08-08" @default.
- W2327862318 modified "2023-10-05" @default.
- W2327862318 title "Gold Nanoparticle Assisted Self-Assembly and Enhancement of Charge Carrier Mobilities of a Conjugated Polymer" @default.
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- W2327862318 doi "https://doi.org/10.1021/jp3039253" @default.
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