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- W2327899137 abstract "本研究は優れた誘電特性を有するポリフッ化ビニリデン(PVDF) I型結晶の作製を目的に行った．PVDFとポリメタクリル酸メチル(PMMA)のブレンド物の溶媒キャスト法による薄膜におけるPVDFの結晶構造の制御を試みた．PVDF/PMMA＝60：40 wt%のブレンド物をジメチルホルムアミド(DMF)溶媒に120℃で溶解した．溶媒キャスト後にフィルムを150℃のホットプレートでベークした後，200℃で溶融し直ちに氷水で冷却し，その後120℃で1日間熱処理した．その結果，PMMA存在下でPVDF I型の結晶のみが優先的に成長することを明らかにした．他のブレンド比のものは，PVDF II型かアモルファスの状態を示した．上記ブレンド比は，すべてのブレンド比の中で最もPVDFとPMMAの相溶状態が優れていると考えられる．その結果，PVDFの結晶化が抑制され，PVDFの結晶化速度が遅くなりPVDF I型の結晶構造が出現したと考察した．" @default.
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- W2327899137 date "2012-01-01" @default.
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- W2327899137 title "Crystal Structure Control of Poly(vinylidene fluoride) (PVDF) in the Blend Films of PVDF and Poly(methyl methacrylate) (PMMA) Prepared by Solvent Casting" @default.
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