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• W2327960051 endingPage "930" @default.
• W2327960051 startingPage "918" @default.
• W2327960051 abstract "Copper(I) and silver(I) ionic compounds [(L)M{(μ3-NH)3Ti3(η5-C5Me5)3(μ3-N)}][O3SCF3] containing [MTi3N4] cube-type cations have been prepared by reaction of [(CF3SO2O)M{(μ3-NH)3Ti3(η5-C5Me5)3(μ3-N)}] (M = Cu (2), Ag (3)) with a variety of donor molecules L. Treatment of complexes 2 and 3 with NH3 in toluene at room temperature gives the ammonia adducts [(H3N)M{(μ3-NH)3Ti3(η5-C5Me5)3(μ3-N)}][O3SCF3] (M = Cu (4), Ag (5)), whose X-ray crystal structures reveal two cube-type cations associated through hydrogen bonding interactions between the ammine ligands and one oxygen atom of each trifluoromethanesulfonate anion. Analogous treatment of 2 and 3 with 1 equiv of pyridine, 2,6-dimethylphenylisocyanide, tert-butylisocyanide, or triphenylphosphane gives the ionic compounds [(L)M{(μ3-NH)3Ti3(η5-C5Me5)3(μ3-N)}][O3SCF3] (L = py, M = Cu (6), Ag (7); L = CNAr, M = Cu (8), Ag (9); L = CNtBu, M = Cu (10), Ag (11); L = PPh3, M = Cu (12), Ag (13)). The reactions of 2 and 3 with methylenebis(diphenylphosphane) (dppm) in a 1:1 ratio lead to the single-cube complexes [(dppm)M{(μ3-NH)3Ti3(η5-C5Me5)3(μ3-N)}][O3SCF3] (M = Cu (14), Ag (15)), whereas in a 2:1 ratio give the bisphosphane-bridged double-cube compounds [{M(μ3-NH)3Ti3(η5-C5Me5)3(μ3-N)}2(μ-dppm)][O3SCF3]2 (M = Cu (16), Ag (17)). Similarly, treatment of 2 or 3 with a half equivalent of ethane-1,2-diylbis(diphenylphosphane) (dppe) affords double-cube derivatives [{M(μ3-NH)3Ti3(η5-C5Me5)3(μ3-N)}2(μ-dppe)][O3SCF3]2 (M = Cu (18), Ag (19)). The X-ray crystal structures of 4, 5, 10, 14, 15, and 18 have been determined." @default.
• W2327960051 created "2016-06-24" @default.
• W2327960051 creator A5035903589 @default.
• W2327960051 creator A5062229377 @default.
• W2327960051 creator A5064413621 @default.
• W2327960051 creator A5072425054 @default.
• W2327960051 creator A5085065303 @default.
• W2327960051 date "2012-12-26" @default.
• W2327960051 modified "2023-10-16" @default.
• W2327960051 title "Copper(I) and Silver(I) Complexes Supported by the Tridentate [{Ti(η⁵-C₅Me₅)(μ-NH)}₃(μ₃-N)] Metalloligand" @default.
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• W2327960051 doi "https://doi.org/10.1021/ic302113k" @default.
• W2327960051 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23268605" @default.
• W2327960051 hasPublicationYear "2012" @default.

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