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- W2327981407 abstract "A number of unassigned lines in the absorption spectrum of diatomic hydrogen are attributed to nominally forbidden transitions from the ground state to the $nf$ manifold of states (Rydberg electron with $ensuremath{ell}=3$ orbital momentum). They appear via weak $ensuremath{ell}ensuremath{-}$ mixing interactions leading to local level perturbations. Our analysis is based on multichannel quantum defect theory and uses known theoretical information from the literature. The upper levels of most of these transitions are known to give rise to molecular fluorescence, and they are shown to be singlet-triplet mixed. We conclude that the well-known metastable $c{phantom{rule{0.16em}{0ex}}}^{3}{mathrm{ensuremath{Pi}}}_{u}^{ensuremath{-}}$ state can be populated via one-photon absorption of uv photons followed by cascade emission $4fensuremath{rightarrow}3densuremath{rightarrow}2p$." @default.
- W2327981407 created "2016-06-24" @default.
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- W2327981407 date "2016-03-22" @default.
- W2327981407 modified "2023-10-02" @default.
- W2327981407 title "Direct optical access to the triplet manifold of states inH2" @default.
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- W2327981407 doi "https://doi.org/10.1103/physreva.93.032514" @default.
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