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- W2327989819 abstract "We present a combined neutron diffraction and bulk thermodynamic study of the natural mineral linarite PbCuSO4(OH)2, this way establishing the nature of the ground-state magnetic order. An incommensurate magnetic ordering with a propagation vector k=(0,0.186,1/2) was found below T(N)=2.8 K in a zero magnetic field. The analysis of the neutron diffraction data yields an elliptical helical structure, where one component (0.638μ(B)) is in the monoclinic ac plane forming an angle with the a axis of 27(2)°, while the other component (0.833μ(B)) points along the b axis. From a detailed thermodynamic study of bulk linarite in magnetic fields up to 12 T, applied along the chain direction, a very rich magnetic phase diagram is established, with multiple field-induced phases, and possibly short-range-order effects occurring in high fields. Our data establish linarite as a model compound of the frustrated one-dimensional spin chain, with ferromagnetic nearest-neighbor and antiferromagnetic next-nearest-neighbor interactions. Long-range magnetic order is brought about by interchain coupling 1 order of magnitude smaller than the intrachain coupling." @default.
- W2327989819 created "2016-06-24" @default.
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- W2327989819 date "2012-03-16" @default.
- W2327989819 modified "2023-09-23" @default.
- W2327989819 title "Magnetic Frustration in a Quantum Spin Chain: The Case of Linarite<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:msub><mml:mi>PbCuSO</mml:mi><mml:mn>4</mml:mn></mml:msub><mml:mo stretchy=false>(</mml:mo><mml:mi>OH</mml:mi><mml:msub><mml:mo stretchy=false>)</mml:mo><mml:mn>2</mml:mn></mml:msub></mml:math>" @default.
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- W2327989819 doi "https://doi.org/10.1103/physrevlett.108.117202" @default.
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