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- W2327989903 abstract "In this communication, we report an easy method for introducing functional groups into polymer structures by successively reacting two different activated ester functionalities (pentafluorophenyl (PFP) ester and azlactone (AZ)) with different functional amine compounds. By exploiting the difference in reactivity of the two activated esters (PFP and AZ) toward different amino compounds, we demonstrate, for the first time, a selective modification of the different activated ester groups, thereby introducing functional groups to the polymer backbone in a controlled manner. Statistical and block copolymers of vinyl dimethyl azlactone (VDM) and pentafluorophenyl acrylate (PFPA), i.e.,(p(VDM-stat-PFPA)) and (p(VDM-block-PFPA)), were prepared using reversible addition-fragmentation transfer (RAFT) polymerization and subsequently modified using a library of amino compounds, yielding macromolecules with bespoke functionality. In additional work, the functional macromolecules were self-assembled into nanoparticles." @default.
- W2327989903 created "2016-06-24" @default.
- W2327989903 creator A5001395511 @default.
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- W2327989903 date "2013-09-25" @default.
- W2327989903 modified "2023-10-07" @default.
- W2327989903 title "Selective Postmodification of Copolymer Backbones Bearing Different Activated Esters with Disparate Reactivities" @default.
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- W2327989903 doi "https://doi.org/10.1021/mz4004375" @default.
- W2327989903 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35607013" @default.
- W2327989903 hasPublicationYear "2013" @default.
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