Matches in SemOpenAlex for { <https://semopenalex.org/work/W2327990596> ?p ?o ?g. }
- W2327990596 endingPage "2246" @default.
- W2327990596 startingPage "2238" @default.
- W2327990596 abstract "The reactions of molecular tantalum and niobium monoxides and dioxides with water were investigated by matrix isolation infrared spectroscopy. In solid neon, the metal monoxide and dioxide molecules reacted with water to form the MO(H2O) and MO2(H2O) (M = Ta, Nb) complexes spontaneously on annealing. The MO(H2O) complexes photochemically rearranged to the more stable HMO(OH) isomers via one hydrogen atom transfer from water to the metal center under visible light excitation. In contrast, the MO2(H2O) complexes isomerized to the more stable MO(OH)2 molecules via a hydrogen atom transfer from water to one of the oxygen atoms of metal dioxide upon visible light irradiation. The aforementioned species were identified by isotopic-substituted experiments as well as density functional calculations." @default.
- W2327990596 created "2016-06-24" @default.
- W2327990596 creator A5011324779 @default.
- W2327990596 creator A5046362125 @default.
- W2327990596 creator A5049936341 @default.
- W2327990596 creator A5070971220 @default.
- W2327990596 date "2011-02-28" @default.
- W2327990596 modified "2023-10-18" @default.
- W2327990596 title "Matrix Isolation Spectroscopic and Theoretical Study of Water Adsorption and Hydrolysis on Molecular Tantalum and Niobium Oxides" @default.
- W2327990596 cites W1969808751 @default.
- W2327990596 cites W1971454456 @default.
- W2327990596 cites W1972227473 @default.
- W2327990596 cites W1978608443 @default.
- W2327990596 cites W1980317465 @default.
- W2327990596 cites W1984293906 @default.
- W2327990596 cites W1986463796 @default.
- W2327990596 cites W1988281028 @default.
- W2327990596 cites W1993077801 @default.
- W2327990596 cites W1998563616 @default.
- W2327990596 cites W2002263502 @default.
- W2327990596 cites W2007788951 @default.
- W2327990596 cites W2008907019 @default.
- W2327990596 cites W2010591550 @default.
- W2327990596 cites W2015723183 @default.
- W2327990596 cites W2020251244 @default.
- W2327990596 cites W2022007076 @default.
- W2327990596 cites W2022357645 @default.
- W2327990596 cites W2023271753 @default.
- W2327990596 cites W2024048945 @default.
- W2327990596 cites W2026048300 @default.
- W2327990596 cites W2026060996 @default.
- W2327990596 cites W2026951207 @default.
- W2327990596 cites W2031554285 @default.
- W2327990596 cites W2033016667 @default.
- W2327990596 cites W2034361155 @default.
- W2327990596 cites W2035736851 @default.
- W2327990596 cites W2036318468 @default.
- W2327990596 cites W2037404442 @default.
- W2327990596 cites W2037663510 @default.
- W2327990596 cites W2039392944 @default.
- W2327990596 cites W2043067244 @default.
- W2327990596 cites W2043185602 @default.
- W2327990596 cites W2045825427 @default.
- W2327990596 cites W2046561845 @default.
- W2327990596 cites W2052754645 @default.
- W2327990596 cites W2054773742 @default.
- W2327990596 cites W2056534146 @default.
- W2327990596 cites W2058687766 @default.
- W2327990596 cites W2062058269 @default.
- W2327990596 cites W2065569073 @default.
- W2327990596 cites W2068031432 @default.
- W2327990596 cites W2069424100 @default.
- W2327990596 cites W2075557069 @default.
- W2327990596 cites W2075917741 @default.
- W2327990596 cites W2078852350 @default.
- W2327990596 cites W2084544286 @default.
- W2327990596 cites W2084620805 @default.
- W2327990596 cites W2089708541 @default.
- W2327990596 cites W2091126018 @default.
- W2327990596 cites W2102807619 @default.
- W2327990596 cites W2133266834 @default.
- W2327990596 cites W2139916893 @default.
- W2327990596 cites W2143981217 @default.
- W2327990596 cites W2144324325 @default.
- W2327990596 cites W2158890208 @default.
- W2327990596 cites W2167812127 @default.
- W2327990596 cites W2314088924 @default.
- W2327990596 cites W2322961427 @default.
- W2327990596 cites W2326847115 @default.
- W2327990596 cites W2330556416 @default.
- W2327990596 cites W2890261304 @default.
- W2327990596 cites W2949245341 @default.
- W2327990596 cites W296215859 @default.
- W2327990596 cites W4240035468 @default.
- W2327990596 cites W4241630216 @default.
- W2327990596 cites W4249430587 @default.
- W2327990596 doi "https://doi.org/10.1021/jp200143y" @default.
- W2327990596 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21355623" @default.
- W2327990596 hasPublicationYear "2011" @default.
- W2327990596 type Work @default.
- W2327990596 sameAs 2327990596 @default.
- W2327990596 citedByCount "15" @default.
- W2327990596 countsByYear W23279905962012 @default.
- W2327990596 countsByYear W23279905962013 @default.
- W2327990596 countsByYear W23279905962014 @default.
- W2327990596 countsByYear W23279905962017 @default.
- W2327990596 countsByYear W23279905962018 @default.
- W2327990596 countsByYear W23279905962021 @default.
- W2327990596 crossrefType "journal-article" @default.
- W2327990596 hasAuthorship W2327990596A5011324779 @default.
- W2327990596 hasAuthorship W2327990596A5046362125 @default.
- W2327990596 hasAuthorship W2327990596A5049936341 @default.
- W2327990596 hasAuthorship W2327990596A5070971220 @default.
- W2327990596 hasConcept C147789679 @default.
- W2327990596 hasConcept C150394285 @default.
- W2327990596 hasConcept C153642686 @default.
- W2327990596 hasConcept C178790620 @default.
- W2327990596 hasConcept C179104552 @default.