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• W2328035966 abstract "We present the first synthesis and characterization of a 1,3-dihydro-1,3-azaborine, a long-sought BN isostere of benzene. 1,3-Dihydro-1,3-azaborine is a stable structural motif with considerable aromatic character as evidenced by structural analysis and its reaction chemistry. Single crystal X-ray analysis indicates bonding consistent with significant electron delocalization. 1,3-Dihydro-1,3-azaborines also undergo nucleophilic substitutions at boron and electrophilic aromatic substitution reactions. In view of the versatility and impact of aromatic compounds in the biomedical field and in materials science, the present study further expands the available chemical space of arenes via BN/CC isosterism." @default.
• W2328035966 created "2016-06-24" @default.
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• W2328035966 date "2011-11-21" @default.
• W2328035966 modified "2023-10-08" @default.
• W2328035966 title "A 1,3-Dihydro-1,3-azaborine Debuts" @default.
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• W2328035966 doi "https://doi.org/10.1021/ja2097089" @default.
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