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• W2328059324 startingPage "4883" @default.
• W2328059324 abstract "Ion dynamics in alkali borohydrides, LiBH4, NaBH4, and KBH4, was studied by solid-state NMR. NMR spectra and spin–lattice relaxation times, T1, of 1H and 11B were measured and analyzed. The T1 results of 1H and 11B indicated that two types of motions take place in the low-temperature (LT) phase of LiBH4. The second moments of 1H and 11B NMR spectra suggested that the sum of the two types of motions resembles isotropic reorientation of the BH4 unit. The T1 minimum values of 1H and 11B supported that the C3 rotation takes place at first. The second type of motion might be either C3 rotation or C2 rotation. The second moments of NMR spectra and the T1 minimum values of 1H and 11B supported that the BH4 unit reorients isotropically in NaBH4 and KBH4." @default.
• W2328059324 created "2016-06-24" @default.
• W2328059324 creator A5080982499 @default.
• W2328059324 creator A5088116463 @default.
• W2328059324 date "2012-02-10" @default.
• W2328059324 modified "2023-10-07" @default.
• W2328059324 title "Reorientational Motion of BH₄ Ions in Alkali Borohydrides MBH₄ (M = Li, Na, K) as Studied by Solid-State NMR" @default.
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• W2328059324 doi "https://doi.org/10.1021/jp300092q" @default.
• W2328059324 hasPublicationYear "2012" @default.
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