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- W2328131405 endingPage "9760" @default.
- W2328131405 startingPage "9751" @default.
- W2328131405 abstract "Three triarylboron- (Mes2BAr-) functionalized dipicolinic acids, namely, 4-(4-(dimesitylboranyl)-2,3,5,6-tetramethylphenyl)pyridine-2,6-dicarboxylic acid (H2L1), 4-(4-(4-dimesitylboranyl)-2,3,5,6-tetramethylphenyl)-1H-1,2,3-triazol-1-yl)pyridine-2,6-dicarboxylic acid (H2L2), and 4-(4-(4-dimesitylboranyl) phenyl)-1H-1,2,3-triazol-1-yl)pyridine-2,6-dicarboxylic acid (H2L3), have been designed and synthesized. Lanthanide(III) complexes with the general formula of [NBu4]3[LnL3] (Ln = Eu or Tb; L = L1, L2, or L3) were obtained. The new triarylboron-functionalized ligands were found to be effective in the selective sensitization of the emissions of Eu(III) and Tb(III) ions with a high quantum efficiency (e.g., 0.54 for [NBu4]3[TbL13] in the solid state) upon excitation at ∼330 nm. An intraligand charge-transfer (ILCT) transition from the mesityl or aryl group to the boron or boron-aryl unit was found to play a key role in the activation of the Eu(III) and Tb(III) emissions, based on TD-DFT computational data and luminescence titration experiments performed using fluoride and cyanide ions." @default.
- W2328131405 created "2016-06-24" @default.
- W2328131405 creator A5023317620 @default.
- W2328131405 creator A5052987611 @default.
- W2328131405 creator A5057524603 @default.
- W2328131405 creator A5069708981 @default.
- W2328131405 date "2014-08-22" @default.
- W2328131405 modified "2023-09-24" @default.
- W2328131405 title "Selective Sensitization of Eu(III) and Tb(III) Emission with Triarylboron-Functionalized Dipicolinic Acids" @default.
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- W2328131405 doi "https://doi.org/10.1021/ic501335e" @default.
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- W2328131405 hasPublicationYear "2014" @default.
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