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- W2328162388 abstract "The synthesis of a pentadentate NNNNN bis(phosphinimine)carbazole pincer ligand bearing two pyrimidine N-aryl rings is reported. A dialkyl lutetium complex of the ligand, prepared by alkane elimination with Lu(CH2SiMe3)3(THF)2, was found to undergo an unusual transformation involving a double alkyl shift whereby the −CH2SiMe3 groups on the metal migrated to both pyrimidine rings. This migration afforded a final product that featured alkyl-functionalized, dearomatized ligand pyrimidine rings." @default.
- W2328162388 created "2016-06-24" @default.
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- W2328162388 date "2013-07-22" @default.
- W2328162388 modified "2023-09-27" @default.
- W2328162388 title "Organolutetium-Mediated Dearomatization and Functionalization of Pyrimidine Rings" @default.
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- W2328162388 doi "https://doi.org/10.1021/om400413e" @default.
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