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• W2328208120 abstract "Atomically precise thiolate-protected noble metal molecular nanoparticles are a promising class of model nanomaterials for catalysis, optoelectronics, and the bottom-up assembly of true molecular crystals. However, these applications have not fully materialized due to a lack of ligand exchange strategies that add functionality, but preserve the properties of these remarkable particles. Here we present a method for the rapid (<30 s) and complete thiolate-for-thiolate exchange of the highly sought after silver molecular nanoparticle [Ag44(SR)30]−4. Only by using this method were we able to preserve the precise nature of the particles and simultaneously replace the native ligands with ligands containing a variety of functional groups. Crucially, as a result of our method we were able to process the particles into smooth thin films, paving the way for their integration into solution-processed devices." @default.
• W2328208120 created "2016-06-24" @default.
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• W2328208120 date "2014-10-31" @default.
• W2328208120 modified "2023-10-05" @default.
• W2328208120 title "Neat and Complete: Thiolate-Ligand Exchange on a Silver Molecular Nanoparticle" @default.
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• W2328208120 doi "https://doi.org/10.1021/ja508860b" @default.
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• W2328208120 hasPublicationYear "2014" @default.
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