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• W2328272020 startingPage "13232" @default.
• W2328272020 abstract "A new small-pore germanosilicate zeolite, named as ITQ-49, has been synthesized using a new ditetraalkylphosphonium dication as an organic structure-directing agent, and its structure has been solved by direct methods applied to the powder X-ray diffraction pattern of the calcined solid. This new zeolite crystallizes in the space group Immm with cell parameters a = 19.6007(8) Å, b = 18.3274(7) Å, and c = 16.5335(6) Å. The pore topology of ITQ-49 consists of large, nonspherical cavities that are connected to each other through small eight-membered-ring windows, resulting in a unidirectional small-pore zeolite that has a relatively large adsorption capacity. Also, ITQ-49 contains double four-membered-ring units where Ge is preferentially located, and fluoride anions are placed inside these units." @default.
• W2328272020 created "2016-06-24" @default.
• W2328272020 creator A5000454699 @default.
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• W2328272020 date "2012-08-06" @default.
• W2328272020 modified "2023-10-11" @default.
• W2328272020 title "Synthesis and Structure Determination of a New Microporous Zeolite with Large Cavities Connected by Small Pores" @default.
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• W2328272020 doi "https://doi.org/10.1021/ja306013k" @default.
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