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- W2328276066 abstract "The effects solvents have on fluoride-promoted heterogeneous hydrolysis and alcoholysis of various organo-phosphorus (OP) compounds on the surface of KF/Al2O3 are described. Solid-state magic angle spinning NMR analyses and SEM microscopy have shown that not only is the identity of the solvent important in these reactions but also its quantity. That is, minimal solvent amounts are favored and much more effective in such solid-supported reactions (and maybe generally) than those featuring solvent-free or excess solvent (>50 wt %) conditions. The addition of a minute quantity of the correct solvent (3–10 wt %, molar equivalent scale) avoids reagents leaching from the matrix, permits mobility (mass transport) of the reaction components and ensures their very high local concentration in close proximity to the solid-support large porous surface area. Accordingly, significant acceleration of reactions rates by orders of magnitude is obtained. Fascinatingly, even challenging phosphoesters with poor leaving groups, which were found to be very stable in the presence of solvent-free KF/Al2O3 or wetted with excess water, were efficiently hydrolyzed with a minute amount of this solvent." @default.
- W2328276066 created "2016-06-24" @default.
- W2328276066 creator A5040903878 @default.
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- W2328276066 date "2015-05-01" @default.
- W2328276066 modified "2023-09-25" @default.
- W2328276066 title "Component Mobility by a Minute Quantity of the Appropriate Solvent as a Principal Motif in the Acceleration of Solid-Supported Reactions" @default.
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- W2328276066 doi "https://doi.org/10.1021/acs.joc.5b00492" @default.
- W2328276066 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25901764" @default.
- W2328276066 hasPublicationYear "2015" @default.
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