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- W2328310523 abstract "Conversion of lignin into value-added chemicals is attracting growing attention due to the depletion of fossil fuels and the abundant resource of lignin. In this study, hydrothermal conversion of a model compound of lignin, catechol, into value-added four-carbon dicarboxylic acids (C4-DCAs), such as tartaric (HOOC–CH(OH)–CH(OH)–COOH), malic (HOOC–CH2–CH(OH)–COOH), and fumaric (HOOC—CH═CH—COOH) acids was investigated. The yield of total C4-DCAs can reach as high as 41.0%, and alkali played a key role in not only promoting the production but also avoiding the decomposition of C4-DCAs. The reaction mechanism of hydrothermal conversion catechol into C4-DCAs showed that catechol is first oxidized to o-quinone, which is then attacked by the hydroxyl radical (OH•) or the hydroperoxyl anion (HO2–) via conjugate addition to decompose into C4-DCAs. This result is helpful to facilitate studies for developing a new, green, and sustainable process to produce value-added C4-DCAs from lignin." @default.
- W2328310523 created "2016-06-24" @default.
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- W2328310523 date "2015-01-02" @default.
- W2328310523 modified "2023-10-16" @default.
- W2328310523 title "Hydrothermal Conversion of Catechol into Four-Carbon Dicarboxylic Acids" @default.
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- W2328310523 doi "https://doi.org/10.1021/ie5036447" @default.
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