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• W2328333875 abstract "Although the pyramidal inversion barriers in diphosphines (R2P–PR2) are similar to those in phosphines (PR3), P-stereogenic chiral diphosphines have rarely been exploited as building blocks in asymmetric synthesis. The synthesis, reactivity, and resolution of the benzodiphosphetane trans-1,2-(P(t-Bu))2C6H4 are reported. Alkylation with MeOTf followed by addition of a nucleophile gave the useful C2-symmetric P-stereogenic ligand BenzP* and novel analogues." @default.
• W2328333875 created "2016-06-24" @default.
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• W2328333875 date "2012-08-07" @default.
• W2328333875 modified "2023-09-25" @default.
• W2328333875 title "Synthesis, Reactivity, and Resolution of a <i>C</i>₂–Symmetric, P–Stereogenic Benzodiphosphetane, a Building Block for Chiral Bis(phosphines)" @default.
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• W2328333875 doi "https://doi.org/10.1021/ol301935q" @default.
• W2328333875 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22870878" @default.
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