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• W2328342860 endingPage "431" @default.
• W2328342860 startingPage "426" @default.
• W2328342860 abstract "The formal [2 + 2] cycloaddition–retroelectrocyclization reaction was employed as the key transformation to obtain donor-substituted, π-conjugated polycyanohexa-1,3,5-trienes (TCHTs and PCHTs) and polycyanoocta-1,3,5,7-tetraenes from donor-substituted tetracyanobuta-1,3-dienes (TCBDs) and electron-rich alkynes. These push–pull-substituted oligoene chromophores were also accessed in good yield from tetracyanoethylene and donor-substituted alkynes by using a one-pot protocol. All bis-(N,N-dialkylanilino) donor-substituted push–pull trienes and tetraenes showed better electron-accepting potency and lower HOMO–LUMO gaps than the corresponding TCBDs, as evidenced by optical and electrochemical studies." @default.
• W2328342860 created "2016-06-24" @default.
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• W2328342860 date "2013-12-11" @default.
• W2328342860 modified "2023-10-17" @default.
• W2328342860 title "One-Pot Access to Push–Pull Oligoenes by Sequential [2 + 2] Cycloaddition–Retroelectrocyclization Reactions" @default.
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• W2328342860 doi "https://doi.org/10.1021/jo402440m" @default.
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