Matches in SemOpenAlex for { <https://semopenalex.org/work/W2328367455> ?p ?o ?g. }
- W2328367455 endingPage "4997" @default.
- W2328367455 startingPage "4988" @default.
- W2328367455 abstract "A density functional theory (DFT) approach based on a weighted density approximation has been employed to study the perpendicular microphase separation of symmetric binary polymer brushes with weak incompatibility in explicit solvents with different selectivities. Characterized by the relation between the grand potential and vertical structures (including nonlayered and layered structures), a dry binary brush can be categorized as W-type or U-type according to whether the characteristic relation contains a structure that undergoes spontaneous symmetry breaking. A W-type brush can memorize the selectivity of the induced solvent in one of its two layered structures after the removal of solvent, which can be seen as a kind of lock state with the nonselective solvent used as its key to unlock. A U-type brush is lockless but can adapt to the environment without the nonselective solvent's triggering. Also, the boundary described in chain-length-incompatibility space is investigated by the DFT approach, which also verifies that the spontaneous symmetry breaking of the W-type brush originates from the molecular contributions to asymmetry, such as the enthalpic contribution of incompatibility and the entropic contribution of chain connectivity." @default.
- W2328367455 created "2016-06-24" @default.
- W2328367455 creator A5008770047 @default.
- W2328367455 creator A5033680548 @default.
- W2328367455 creator A5040301471 @default.
- W2328367455 creator A5045256518 @default.
- W2328367455 creator A5077193653 @default.
- W2328367455 creator A5078188641 @default.
- W2328367455 date "2013-04-09" @default.
- W2328367455 modified "2023-09-23" @default.
- W2328367455 title "Lock/Unlock Mechanism of Solvent-Responsive Binary Polymer Brushes: Density Functional Theory Approach" @default.
- W2328367455 cites W1966806479 @default.
- W2328367455 cites W1966908669 @default.
- W2328367455 cites W1971001565 @default.
- W2328367455 cites W1971099347 @default.
- W2328367455 cites W1975819770 @default.
- W2328367455 cites W1975899172 @default.
- W2328367455 cites W1980146478 @default.
- W2328367455 cites W1980836127 @default.
- W2328367455 cites W1981676140 @default.
- W2328367455 cites W1985444137 @default.
- W2328367455 cites W1986595934 @default.
- W2328367455 cites W1986643982 @default.
- W2328367455 cites W1987534450 @default.
- W2328367455 cites W1989200731 @default.
- W2328367455 cites W1989243753 @default.
- W2328367455 cites W1989753177 @default.
- W2328367455 cites W1993764523 @default.
- W2328367455 cites W1996763948 @default.
- W2328367455 cites W1998547353 @default.
- W2328367455 cites W1999568499 @default.
- W2328367455 cites W2001733396 @default.
- W2328367455 cites W2002060883 @default.
- W2328367455 cites W2002654623 @default.
- W2328367455 cites W2011932059 @default.
- W2328367455 cites W2016831453 @default.
- W2328367455 cites W2019552320 @default.
- W2328367455 cites W2019751694 @default.
- W2328367455 cites W2022736096 @default.
- W2328367455 cites W2024087967 @default.
- W2328367455 cites W2024940665 @default.
- W2328367455 cites W2035115178 @default.
- W2328367455 cites W2038747973 @default.
- W2328367455 cites W2040740061 @default.
- W2328367455 cites W2041917136 @default.
- W2328367455 cites W2043636072 @default.
- W2328367455 cites W2043929848 @default.
- W2328367455 cites W2047352623 @default.
- W2328367455 cites W2048343264 @default.
- W2328367455 cites W2048922303 @default.
- W2328367455 cites W2052247022 @default.
- W2328367455 cites W2053215292 @default.
- W2328367455 cites W2053677787 @default.
- W2328367455 cites W2059241329 @default.
- W2328367455 cites W2062612965 @default.
- W2328367455 cites W2066404867 @default.
- W2328367455 cites W2067159153 @default.
- W2328367455 cites W2069661423 @default.
- W2328367455 cites W2070399029 @default.
- W2328367455 cites W2070501056 @default.
- W2328367455 cites W2071211428 @default.
- W2328367455 cites W2078673875 @default.
- W2328367455 cites W2078849857 @default.
- W2328367455 cites W2081378868 @default.
- W2328367455 cites W2084159777 @default.
- W2328367455 cites W2089960265 @default.
- W2328367455 cites W2091683086 @default.
- W2328367455 cites W2101141119 @default.
- W2328367455 cites W2130011159 @default.
- W2328367455 cites W2130884619 @default.
- W2328367455 cites W2138134985 @default.
- W2328367455 cites W2140139772 @default.
- W2328367455 cites W2323632664 @default.
- W2328367455 cites W2324278409 @default.
- W2328367455 cites W2330691705 @default.
- W2328367455 cites W4246652745 @default.
- W2328367455 doi "https://doi.org/10.1021/la304984s" @default.
- W2328367455 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23527584" @default.
- W2328367455 hasPublicationYear "2013" @default.
- W2328367455 type Work @default.
- W2328367455 sameAs 2328367455 @default.
- W2328367455 citedByCount "15" @default.
- W2328367455 countsByYear W23283674552013 @default.
- W2328367455 countsByYear W23283674552014 @default.
- W2328367455 countsByYear W23283674552015 @default.
- W2328367455 countsByYear W23283674552016 @default.
- W2328367455 countsByYear W23283674552017 @default.
- W2328367455 countsByYear W23283674552019 @default.
- W2328367455 countsByYear W23283674552020 @default.
- W2328367455 countsByYear W23283674552021 @default.
- W2328367455 countsByYear W23283674552022 @default.
- W2328367455 crossrefType "journal-article" @default.
- W2328367455 hasAuthorship W2328367455A5008770047 @default.
- W2328367455 hasAuthorship W2328367455A5033680548 @default.
- W2328367455 hasAuthorship W2328367455A5040301471 @default.
- W2328367455 hasAuthorship W2328367455A5045256518 @default.
- W2328367455 hasAuthorship W2328367455A5077193653 @default.
- W2328367455 hasAuthorship W2328367455A5078188641 @default.