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- W2328381321 abstract "We present here for the first time a simple method for micropatterning nonwoven composite membranes. The approach is based on the simultaneous electrospraying of microparticles and electrospinning of nanofibers from different polymer solution feeds (polyethylene glycol and poly(d,l-lactide)) on a common support. The mechanism of self-organization between fibers and particles into hierarchical honeycomb-like structures, as well as the evolution of the later as a function of the thickness of the composite, is investigated. We demonstrate that aggregates of particles, leading to a nonuniform distribution of the electrostatic field near the collector, are necessary to form the self-organized composite. Furthermore, it is shown that the specific dimensions of the generated patterns can be controlled by tuning the flow rate of electrospraying. The obtained composite mat exhibits a multilevel porous structure, with pore sizes ranging from few up to several hundreds of micrometers. Finally, it is shown that the microparticles can be selectively leached, allowing the production of a monocomponent membrane and retaining the hierarchical organization of the nanofibers suitable for biomedical and filtration applications." @default.
- W2328381321 created "2016-06-24" @default.
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- W2328381321 date "2013-10-07" @default.
- W2328381321 modified "2023-10-18" @default.
- W2328381321 title "Simultaneous Electrospinning and Electrospraying: A Straightforward Approach for Fabricating Hierarchically Structured Composite Membranes" @default.
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- W2328381321 doi "https://doi.org/10.1021/am402676m" @default.
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