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- W2328426742 abstract "The photoassisted hydrogen storage in rare earth intermetallic compounds (R2Co7 and RCo3)has been investigated using methanol or 2-propanol as a hydrogen carrier. Though the hydriding kinetics was negligibly small at room temperature, the irradiation by a highpressure mercury vapor lamp accelerated the reaction much rapidly. When the powders of rare earth intermetallic compounds were dispersed in a solution of alcohol with CCl4 and irradiated at room temperature, the alloy was transfer-hydrogenated to form metal hydrides by the photodehydrogenation of alcohol. Irradiation of Sm2Co7 (ca. O.3 g) for 3 h in a solution of 2-propanol (220 cm3) with CCl4 (0.05 cm3) resulted in the formation of α+β hydrides. It is concluded that upon irradiation of alloys in alcohol-CCl4, the photodehydro genation of alcohol occurred to produce dehydrogenated products and hydrogen in the form of hydride." @default.
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- W2328426742 date "1988-01-01" @default.
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- W2328426742 title "Photoassisted hydrogen storage in rare earth intermetallic compounds. Transfer hydrogenation by the use of alcohol." @default.
- W2328426742 doi "https://doi.org/10.1246/nikkashi.1988.1235" @default.
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