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- W2328528050 abstract "The electrocatalytic activity of a series of Co macrocyclic complexes confined on graphite electrodes for the oxidation of thiols : 2mercaptoethanol, 2-mercaptoacetate, 2-aminoethanethiol and l-cysteine give volcano correlations between catalytic activity of the metallo complexes and the formal potential of the complex. The formal potential that gives the maximum activity correlates linearly with the pKa of the thiol. We have extended previous studies for the oxidation of hydrazine using Co and Fe macrocyclics and obtain volcano correlations for this reaction as well. The slope of the rising region of the volcano (where the catalytic activity increases with the driving force of the catalyst) gives values of ca. +0.120 V/decade which is the theoretical value when using a Langmuir isotherm for the adsorbed thiol or hydrazine molecule on the reacting site. These results indicate that is possible to tune the redox potential of the complexes to attain maximum activity." @default.
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- W2328528050 date "2009-11-30" @default.
- W2328528050 modified "2023-10-11" @default.
- W2328528050 title "Tuning the Formal Potential of Metallomacrocyclics for Maximum Catalytic Activity For the Oxidation of Thiols and Hydrazine" @default.
- W2328528050 cites W2145884973 @default.
- W2328528050 doi "https://doi.org/10.1149/1.3268166" @default.
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