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• W2328552934 abstract "A 364-nm negative-ion photoelectron spectrum of CH3S− has been recorded. The electron affinity is 1.867±0.004 eV. Well-resolved vibrational structure has been observed such that the C–S symmetric stretch and the C–H symmetric stretch have been measured at 725±15 cm−1 and 1260±30 cm−1, respectively. The spin–orbit splitting is reported at 265±15 cm−1. The large spin–orbit splitting quenches the Jahn–Teller modes seen in the analogous radicals, CH3O and CF3S." @default.
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• W2328552934 date "2000-07-01" @default.
• W2328552934 modified "2023-09-24" @default.
• W2328552934 title "Negative-ion photoelectron spectroscopy of CH3S−" @default.
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• W2328552934 doi "https://doi.org/10.1016/s0368-2048(00)00125-0" @default.
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