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• W2328699618 abstract "The reactions of lithium ion battery electrolyte (LiPF6 in ethylene carbonate/ethyl methyl, EC/EMC, 3:7 v/v) with and without added lithium bis(oxalato) borate (LiBOB) on the surface of high voltage LiNi0.5Mn1.5O4 cathodes has been investigated via a combination of electrochemical measurements, in situ gas analysis, and ex situ surface analysis. The oxidation of LiBOB on the cathode results in the generation of CO2 and a cathode passivation film containing borate oxalates. The cathode passivation film inhibits oxidation of the bulk electrolyte at high potential (>4.8 V vs Li/Li+)." @default.
• W2328699618 created "2016-06-24" @default.
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• W2328699618 date "2014-03-27" @default.
• W2328699618 modified "2023-09-26" @default.
• W2328699618 title "Generation of Cathode Passivation Films via Oxidation of Lithium Bis(oxalato) Borate on High Voltage Spinel (LiNi_0.5Mn_1.5O₄)" @default.
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• W2328699618 doi "https://doi.org/10.1021/jp501970j" @default.
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