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• W2328709802 startingPage "15687" @default.
• W2328709802 abstract "Polymer substrates have been functionalized with a MOF material (MIL-47) synthesized directly on polyacrylonitrile using in situ microwave irradiation. The growth of MIL-47 on these substrates was studied as a function of microwave irradiation time using scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. The conversion of nitrile to carboxylic acid groups on the PAN surface was necessary for the growth of MIL-47 on the substrate. MIL-47 crystals grew over time at the expense of a related disordered precursor phase, which lacks the long-range order of MIL-47. This work paves the way for the development of a new class of hybrid MOF-polymer materials that will extend the applications of MOFs to fields such as membrane separations, filtration, and protective textiles." @default.
• W2328709802 created "2016-06-24" @default.
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• W2328709802 date "2010-10-14" @default.
• W2328709802 modified "2023-10-11" @default.
• W2328709802 title "Growth of Metal−Organic Frameworks on Polymer Surfaces" @default.
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• W2328709802 doi "https://doi.org/10.1021/ja106381x" @default.
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