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• W2328751710 abstract "Three grades of PolyActive block copolymers are investigated for CO2 separation from light gases. The polymers are composed of 23 wt % poly(butylene terephthalate) (PBT) and 77 wt % poly(ethylene glycol terephthalate) (PEGT) having the poly(ethylene glycol) segments of 1500, 3000, and 4000 g/mol, respectively. A commercial PEG POSS (poly(ethylene glycol) functionalized polyoctahedral oligomeric silsesquioxanes) is used as a nanofiller for these polymers to prepare nanocomposites via a solvent casting method. Single gas permeabilities of N2, H2, CH4, and CO2 are measured via the time-lag method in the temperature range from 30 to 70 °C. The thermal transitions of the prepared membranes are studied by differential scanning calorimetry (DSC). It is found that the length of PEG segment has a pronounced influence on the thermal transition of the polymers that regulates the gas separation performance of the membranes. The stability of the nanocomposites is also correlated with the thermal transition of the polyether blocks of the polymer matrices." @default.
• W2328751710 created "2016-06-24" @default.
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• W2328751710 date "2014-09-30" @default.
• W2328751710 modified "2023-09-24" @default.
• W2328751710 title "Influence of Poly(ethylene glycol) Segment Length on CO₂ Permeation and Stability of PolyActive Membranes and Their Nanocomposites with PEG POSS" @default.
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• W2328751710 doi "https://doi.org/10.1021/am504223f" @default.
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